Hey ADL, Brian emailed me a while back about this and all you gotta do, he said, is to extrude the edge a little bit that you want thicker, smooth once, check it out, and go back and extrude again if you need it thicker/sharper.
For Subd's, go into poly mode, extrude the edge, and go back to SubD mode, choose the SubD edge, and run a partial crease on it.
Hope that helps
Israel "Izzy" Long
Motion and Title Design for Broadcast-Film-DS
izzylong.com